PREPARATION AND CHARACTERIZATION OF NEW IMINE- FUNCTIONAL GROUP FOR FAST REMOVAL OF Cr (III) IN SOME SUPPLEMENTS FROM SHRIMP SHELL
DOI:
https://doi.org/10.36103/6prg8p33Keywords:
extracted chitosan, imine-schiff base, removal of Cr (III).Abstract
A new imine-Schiff base adsorbent is prepared from extracted chitosan to make taking away exoskeletons of crustacean shrimp shells low-cost and environmentally friendly with the fast and high ability to remove Cr (III) from aqueous solution. The resulting composites were verified by different techniques FTIR, H-NMR, FESEM, EDX, XRD. On applying the adsorption kinetic model, the pseudo 2nd order model was best characterised, using adsorption equilibrium data; the Langmuir model provided a superior description. Further, the negative value of ∆G shows a spontaneous process in nature. Finally, the prepared adsorbent has been applied to a real sample of bodybuilder supplements.
References
Antonino, R., B. Fook, V. Lima, R. D. F. Rached, E. Lima, R. S. Lima, C. P. Covas and M. L. Fook, 2017. Preparation and characterization of chitosan obtained from shells of shrimp (Litopenaeus vannamei Boone). Mar. Drugs, 15, 1-12.
Doi.org/10.3390/md15050141.
Ayawei, N., 2017. Augustus Newton Ebelegi, and Donbebe Wankasi. Modelling and interpretation of adsorption isotherms. Hindawi Journal of Chemistry.
Doi.org/10.1155/2017/3039817.
Dao, M. U., H. S. Le, V. D. Doan, and H. T. Nguyen, 2019. Adsorption of Ni (II) ions by magnetic activated carbon/chitosan beads prepared from spent coffee grounds, shrimp shells and green tea extract. Environmental Technology.40,1-49.
Doi.org/10.1080/09593330.2019.1584250
Elavarasan, A. 2018. EDX and XRD, FT-IR spectra, analysis containing hexavalent chromium metal ion adsorption present in aqueous solution on to phosphoric acid (H3PO4) activated Mimusops elengi leaves carbon. Journal of Drug Delivery and Therapeutics, 8, 132-138.
Doi.org/10.22270/jddt.v8i5-s.1917.
Fan, H. T., X. T. Sun, Z. G. Zhang, and W. X. LI, 2014. Selective removal of lead (II) from aqueous solution by an ion-imprinted silica sorbent functionalized with chelating N-donor atoms. Journal of Chemical and Engineering Data, 59, 2106-2114.
Doi.org/10.1021/je500328t.
Gatabi, J., Y. Sarrafi, M. M. Lakouraj, and M. Taghavi, 2020. Facile and efficient removal of Pb (II) from aqueous solution by chitosan-lead ion imprinted polymer network. Chemosphere, 240, 124772.
Doi.org/10.1016/j.chemosphere.2019.124772.
Gokila, S., T. Gomathi, P. Sudha, and S. Anil, 2017. Removal of the heavy metal ion chromiuim (VI) using Chitosan and Alginate nanocomposites. International Journal of Biological Macromolecules, 104, 1459-1468.
Doi.org/10.1016/j.ijbiomac.2017.05.117.
Hassan, R., H. Arida, M. Montasser, and N. Abdel Latif, 2013. Synthesis of new Schiff base from natural products for remediation of water pollution with heavy metals in industrial areas. Journal of Chemistry, 2013.
Doi.org/10.1155/2013/240568.
He, Y., P. Wu, W. Xiao, G. Li, J. Yi, Y. He, C. Chen, P. Ding and Y. Duan, 2019. Efficient removal of Pb (II) from aqueous solution by a novel ion imprinted magnetic biosorbent: adsorption kinetics and mechanisms. PLoS One, 14, e0213377.
Doi.org/10.1371/journal.pone.0213377.
Issa, Y., H. Hassib and H. Abdelaal, 2009. 1H NMR, 13C NMR and mass spectral studies of some Schiff bases derived from 3-amino-1, 2, 4-triazole. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 74, 902-910.
Doi.org/10.1016/j.saa.2009.08.042.
Kocak, N., M. Sahin, G. Arslan, and H. I. Ucan, 2012. Synthesis of crosslinked chitosan possessing schiff base and its use in metal removal. Journal of Inorganic and Organometallic Polymers and Materials, 22, 166-177.
Doi.org/10.1007/s10904-011-9509-3.
Kofa, G., G. Nkoue Ndongo, K. Ngounou, M. Nsoe, E. Amba and S. Ndi Koungou, 2019. Grewia spp. Biopolymer as Low-Cost Biosorbent for Hexavalent Chromium Removal. Journal of Chemistry, 2019.
Doi.org/10.1155/2019/6505731.
Li, H., J. Li, and L. Cheng, 2015. Novel Cr (III) surface magnetic ion-imprinted materials based on graphene oxide for selective removal of Cr (III) in aqueous solution. Desalination and Water Treatment, 56, 204-215.
Doi.org/10.1080/19443994.2015.1025852.
Mafu, L. D., B. B. Mamba, and T. A. Msagati, 2016. Synthesis and characterization of ion imprinted polymeric adsorbents for the selective recognition and removal of arsenic and selenium in wastewater samples. Journal of Saudi Chemical Society, 20, 594-605.
Doi.org/10.1016/j.jscs.2014.12.008.
Monier, M., A. A. H. Bukhari, and N. H. Elsayed, 2020. Designing and characterization of copper (II) ion-imprinted adsorbent based on isatin functionalized chitosan. International Journal of Biological Macromolecules, 155, 795-804.
Doi.org/10.1016/j.ijbiomac.2020.03.215
Mustafa H.N and I. Al -Ogaidi, 2023. Efficacy of zinc sulfide- chitosan nanoparticles against bacterial diabetic wound infection. Iraqi Journal of Agricultural Sciences.54(1):1-17. https://doi.org/10.36103/ijas.v54i1.1671
Nisreen A. J. and M. M. Sirhan,2021. Comparative study of removal pollutants (heavy metals) by agricultural wastes and other chemical from the aqueous solutions. Iraqi Journal of Agricultural Sciences. 52(2):392-402. https://doi.org/10.36103/ijas.v52i2.1300
Neagu, V. 2009. Removal of Cr (VI) onto functionalized pyridine copolymer with amide groups. Journal of Hazardous Materials, 171, 410-416. Doi.org/10.1016/j.jhazmat.2009.06.016.
Nematidil, N., M. Sadeghi, S. Nezami, and H. Sadeghi, 2019. Synthesis and characterization of Schiff-base based chitosan-g-glutaraldehyde/NaMMTNPs-APTES for removal Pb2+ and Hg2+ ions. Carbohydrate Polymers, 222, 114971.
Doi.org/10.1016/j.carbpol.2019.114971.
Puvvada, Y. S., S. Vankayalapati, and S. Sukhavasi, 2012. Extraction of chitin from chitosan from exoskeleton of shrimp for application in the pharmaceutical industry. International Current Pharmaceutical Journal, 1, 258-263.
Raghad N. M and I. A. Abeer. 2023. Adsorption of methylene blue from aqueous solution using free and immobilized algae cells. Iraqi Journal of Agricultural Sciences. 54(5),1387-1397. https://doi.org/10.36103/ijas.v54i5.1839
Ren, Y., M. Zhang, and D. Zhao, 2008. Synthesis and properties of magnetic Cu (II) ion imprinted composite adsorbent for selective removal of copper. Desalination, 228, 135-149.
Doi.org/10.1016/j.desal.2007.08.013
Shahraki, S., H. S. Delarami, F. Khosravi, and R. Nejat, 2020. Improving the adsorption potential of chitosan for heavy metal ions using aromatic ring-rich derivatives. Journal of Colloid and Interface Science, 576, 79-89. Doi.org/10.3390/md15050141.
Thatte, C., M. Rathnam, and A. Pise, 2014. Chitosan-based Schiff base-metal complexes (Mn, Cu, Co) as heterogeneous, new catalysts for the β-isophorone oxidation. Journal of Chemical Sciences, 126, 727-737.
Doi.org/10.1007/s12039-014-0601-4.
Vadivel, T., M. S. Dhamodaran, Kulathooran, and S. Senguttuvan, 2020. Rhodium (III) complexes derived from complexation of metal with azomethine linkage of chitosan biopolymer Schiff base ligand: Spectral, thermal, morphological and electrochemical studies. Carbohydrate Research,487,107878. Doi.org/10.1016/j.carres.2019.107878.
Wahab, M. A., S. Jellali, and N. Jedidi, 2010. Effect of temperature and pH on the biosorption of ammonium onto Posidonia oceanica fibers: Equilibrium, and kinetic modeling studies. Bioresource Technology, 101,8606-8615. Doi.org/10.1016/j.biortech.2010.06.099.
Yunus, K., M. Zuraidah, and A. John, 2020. A review on the accumulation of heavy metals in coastal sediment of Peninsular Malaysia. Ecofeminism and Climate Change.1,1-35.
Doi.org/10.1108/EFCC-03-2020-0003.
Zhang, Y., Z. Bai, W. Luo, L. Zhai, B. Wang, X. Kang, and J. Zong, 2019. Ion imprinted adsorbent for the removal of Ni (II) from waste water: preparation, characterization, and adsorption. Journal of Dispersion Science and Technology, 40, 1751-1760.
Doi.org/10.1080/01932691.2018.1538883.
Zhou, Z., D. Kong and Z. Ren, 2018. Preparation and adsorption characteristics of an ion-imprinted polymer for fast removal of Ni (II) ions from aqueous solution. Journal of Hazardous Materials, 341, 355-364. Doi.org/10.1016/j.jhazmat.2017.06.010.
Downloads
Published
Issue
Section
License
Copyright (c) 2024 IRAQI JOURNAL OF AGRICULTURAL SCIENCES
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
How to Cite
2.jpg)
https://orcid.org/0000-0002-5774-5906 2.jpg)
