ADSORPTION OF COPPER ON SURFACES OF FEASIBLE MATERIALS (PLANT WASTE, SLUDGE AND BENTONITE) METAL)
DOI:
https://doi.org/10.36103/ijas.v53i3.1575Keywords:
preference coefficient, G for adsorption reactions, natural adsorbents.Abstract
Extraction of Copper ion from its water solutions using plant waste (compost), sludge and Bentonite metal as cheap natural adsorbed materials. It was found that Copper ion extraction was based on concentration of Copper and amount of the adsorbed materials. Highest amount of adsorption was obtained at 180 µg Cu ml-1 as Bentonite, plant waste and sludge respectively. Thermal equilibrium of the system was studied by Langmuir equation, R2 gave a good linear relationship in succession. Maximum regulatory capacity and regulatory capacity at equilibrium is 1.0 , 0.99 and 0.96 to plant waste, sludge and Bentonite respectively, as the preference coefficient constant calculated by the Langmuir equation indicate that adsorption is preferable and irriversible for plant waste and sludge while not preferentially and reversible for bentonite. G adsorption reactions were automatic for the Bentonite metal, while for plant waste and sludge non-spontaneous reaction and needs extra activation energy. It is clear from the above that the use of natural materials in the extraction of copper ion is a very effective method and it is an inexpensive and friendly methods envirooment.
References
Abaliwano K. J.; A. K, Ghebremichael and L.G.,Amy.2008. Application of the purified moringa oleifera coagulant for surface water treatment, Water Mill, Working Paper Series, 5: 1-22
Al-Dwairi, R. A. and A. E. Al-Rawajfeh.2012. Removal of cobalt and nickel from wastewater by using Jordan Low-Cost Zeolite and bentonite. Journal of the University of Chemical Technology and Metallurgy, 47(1) : 69-76
Al-Hassoon, S. N. H. 2015. Adsorption and Release of Cd and Zn under Marshes Reigon and its Salts Affected and Water Logged Soils in Effect in Growth and Yield of Wheat(Triticum aestivum L.), Ph.D. Dissertection , Univ.,Baghdad
Al-Hassoon , S. N.H. ; A.S. J. Z. Al-Hayani and M. A.J. Al-Obaidi.2019a. Adsorption Isotherm of Lead on Calcium Carbonate. Iraqi Journal of Agricultural Sciences ,50 (Special Issue):48-53
Al-Hassoon , S. N.H. ; A.S. J. Z. Al-Hayani and M. A.J. Al-Obaidi. 2019b. Copper Adsorption in two different soil texture, Iraqi Journal of Agricultural Sciences:50(2):638-645
Belete T.; A.Hussen and Rao V.M. 2014. Determination of concentrations of selected heavy metals in Cow’s Milk: Borena Zone, Ethiop. J. Health Sci. 4(5): 105-112
Krishnamurti, G.S.R. and R. Naidu .2008. Chemical speciation and bioavailability of trace metals.. In: Violante, A. ; P.M. Huang and G.M. Gadd (eds). Biophysico-Chemical Processes of Heavy Metals and Metalloids in Soil Environments Wiley Inter science, New York: 419-466
Langmuir I.1918. The adsorption of gases on plane surfaces of glass, mica and platinum,J. Am. Chem., 57, 1361–1403
Li, J. S. ; P.Wang and L. Liu. 2013. Environmental prediction model for dynamic release of Lead in contaminated soil under washing remediation . EJGE. (18):55-70
Mousavi, H.Z. and Z.Lotfi. 2012. Adsorption of heavy metal ions on olive leaves: equilibrium and kinetic studies, J.App.Chem., 7 (23): 49-55
Nietoa, L.M.;S.B. Alamia ; G.Hodaifab ; C Faurc ; S Rodrígueza ; J.A.Giméneza and J. Ochandoa.2010. Adsorption of iron on crude olive stones, Ind. Crops Prod.(32): 467-471
OECD. 2006. Improving Water Management: Recent OECD experience, pp: 1-4. Online
Ojedokun, A.T. and Olugbenga, S.B. 2015. An overview of low cost adsorbentsfor Copper (II) Ions removal. Journal of Biotechnology & Biomaterials , (5): 175-177
Rao, K.S.; M Mohapatra ;S. Anand and P.Venkateswarlu. 2010. Review on cadmium removal from aqueous solutions,Int.J. Eng. Sci. Tech., (2): 81-103
Rich, G. and K. Cherry.1987. Hazardous wastes treatment technologies, pudvan publishers, (1): 201-210
Salim, R.; M. Al-Subu and E. Dawod.2008. Efficiency of removal of cadmium from aqueous solutions by plant leaves and the effects of interaction of combinations of leaves on their removal efficiency ,J Environ Manage., 87(5): 21-32
Taha, A. A.; N. J.Hameed, and F. H. Rashid. 2019. Study of toxic heavy metal removal by different chitosan, hyacinths plant composite . Iraqi Journal of Agricultural Sciences. 50 (5): 1416-1424
Tien,C. 2019. Introduction to adsorption: basics, analysis, and applications . Radarweg 29, PO Box 211, 1000 AE Amsterdam, Netherlands, The boulevard, Langford Lane, Kidlington, Oxford OX5 1GB, United Kingdom, 50 Hampshire Street, 5th Floor, Cambridge, MA 02139, United States, ISBN: 978-0-12-816446-4
Venkateswarlu P, M. Venkata Ratnam, DS Rao, and MV Rao.2007. Removal of chromium from an aqueous solution using Azadirachta indica (neem) leaf powder as an adsorbent, Int.J.Phys. Sci, 2 (8), 188-195
Yassen, M.M. and S. J. Fakher,. 2016. Using the equilibrium and thermodynamic parameters of copper adsorption in some calcareous soils. Assiut J. Agric. Sci.,47(6-2:602-614).
Downloads
Published
Issue
Section
License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.