THE EFFICIENCY OF GUM-SILICA CMPOSITE FOR REMOVING OF WASTEWATER TURBIDITY

Authors

  • M. R. Majeed
  • Wafaa W. AL-Qaysi
  • F.H.Abdulla

DOI:

https://doi.org/10.36103/d96s6950

Keywords:

Arabic gum, Rice husk, Heavy metals, AAS, TDS.

Abstract

A novel mixed natural coagulant has been developed to remove sewage pollutants and heavy metals from Qanat- al- Jayesh by using low cost adsorbent natural materials. In these materials, significant interaction contains Arabic gum mixed with extracted silica from rice husk ash (natural coagulants) by the Batch device approach, using two variables, pH values ranging from 5-8 and contact times between 0.25-5 hrs. All wastewater samples were collected after treatment by adsorbents and examined for determination of residual heavy metal concentrations: Pb, Ni, Zn and Cu by atomic absorption spectroscopy (AAS), turbidity, pH, total dissolved salts (TDS), electrical conductivity (EC) and total salinity (TS). The results obtained indicate The coagulation process' highest level of effectiveness was 95.2% for gum-silica composite with the weight 8 gm for reducing turbidity. In comparison, The coagulation process's least effective efficiency was 80.6%, with the weight 4 gm of gum-silica composite. On the other pH values, Turbidity, TDS, TS, and EC were reduced in the waste water sample after being treated by gum-silica composite under standard water values. This mixture can be used to remove heavy water pollutants during treatment.

References

Abdulla, F. H. 2014. Removal of chromium (III) ions from its aqueous solution on adsorbent surfaces: Charcoal, Attapulgite and Date Palm Leaflet Powder. Iraqi Journal of Science, 55(4A), 1415-1430

Ahmed, S., S. Aktar, S. Zaman, R. A. Jahan, and M. L. Bari.2020. Use of natural bio-sorbent in removing dye, heavy metal and antibiotic-resistant bacteria from industrial wastewater. Appl. Water Sci., 10(5)1071-10.https://doi.org/10.1007/s13201 -020-01200-8

Akdemir, E. O.2018. Application of box wilson experimental design method for removal of acid red 95 using ultrafiltration membrane. Membrane Water Treatment, 9(5),309-315.http://dx.doi.org/10.12989/mwt .2018.9.5.309

AL- Fatlawy, Y. F. K., M. R. Majeed, and B. M. Dhedan. 2016. Study of the efficiency of extracted silica from rice husk ash in reducing the concentration of some heavy metal in industrerial wastewater.Iraqi Journal of Science, 57(1A), 66-71

Al-Gheethi, A., E. Noman, B. Jeremiah David, R. Mohamed, A. Abdullah, S. Nagapan, and A. Hashim Mohd. 2018. A review of potential factors contributing to epidemic cholera in Yemen. J. Water Health. 16(5), 667–680. https://doi.org/ 10.2166/wh. 2018.113

Al-Sahari, M., A. Al-Gheethi, and R. Mohamed. 2020. Natural Coagulates For Wastewater Treatment; A Review For Application And Mechanism. Springer Nature Switzerland AG, Ch2, 11-15. https://doi.org/ 10.1007/978-3-030-42641-5_2

Apoorv, S., and R. Khalid. 2014. Physical and chemical properties of rice husk ash and ground granulated blast furnace slag-a review. Glob. J. Eng. Sci. Res., 1(6), 1-5.

Armestoa, L., A. Bahilloa, K.Veijonenb, A.Cabanillasa, and J. Oteroa. 2002. Combustion behaviour of rice husk in a bubbling fluidized bed. Biomass and Bioenergy, 23(3), 171-179.

https://doi. org/10.1016/S0961- 9534(02) 0004 6-6

Balouch, A., M. Kolachi, F.N. Talpur, H. Khan, and M.I. Bhanger. 2013. Sorption kinetics, isotherm and thermodynamic modeling of defluoridation of ground water using natural adsorbents. Am. J. Anal. Chem., 4, 221–228. https://doi.10.4236/ajac.2013.450 28

Batagarawa, S. M., and A. K. Ajibola. 2019. Comparative evaluation for the adsorption of toxic heavy metals on to millet, corn and rice husks as adsorbents, Journal of Analytical & Pharmaceutical Research, 8 (3), 119-125.

http://dx.doi.org/10.15406/japlr.201 9.08. 00325.

Bhattacharya, A.K., S.N. Mandal, and S.K. Das.2006. Adsorption of Zn (II) from aqueous solution by using different adsorbents. Chem. Eng. J., 123, 43–51.

https://doi.org/10.1016/j. cej. 2006.06.012

Boujelben, N., F.Bouhamed, Z. Elouear, J.Bouzid, and M.Feki. 2013. Removal of phosphorus ions from aqueous solutions using manganese-oxide-coated sand and brick. Desalin. Water Treat, 52, 2282–2292. https://doi.org/10.1080/19443994.2013.822324

da Silva Abreu, F. O. M., N. A. da Silva, M.de Sousa Sipauba, T. F. Marques Pires, T.Araújo Bomfim, O. A. de Castro Monteiro Junior, and M. M. de Camargo Forte.2018. Chitosan and gum arabic nanoparticles for heavy metal adsorption. Polímeros, 28(3), 231-238.https://doi.org/10.1590/0104-1428. 02317

Dada, A., A.Olalekan, A.Olatunya, and O.Dada. 2012. Langmuir, freundlich, temkin and dubinin-radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk. J. Appl. Chem., 3(1), 38–45.

https://doi.org/10.10.97 90/5736-0313845

Elbedwehy, A. M., A. M. Abou-Elanwar, A. O. Ezzat, and A. M. Atta. 2019. Super effective removal of toxic metals water pollutants using multi functionalized poly acrylonitrile and arabic gum grafts. Polymers (Basel)., 11(12), 1938-1954. https://doi:10. 3390/ polym11121938

Elsheikh, M. A., and W. K. Al-Hemaidi, 2012. Approach in choosing suitable technology for industrial wastewater treatment. J. Civil Environ Eng., 2(5) 123, 1-10. https://doi.org/10. 10.4172/2165-784X. 1000123

Errich, A., K. Azzaoui, E. Mejdoubi, B. Hammouti, N. Abidi, N. Akartasse, L. Benidire, S. EL Hajjaji, R. Sabbahi, and A. Lamhamdi. 2021. Toxic heavy metals removal using a hydroxyapatite and hydroxyethyl cellulose modified with a new gum arabic. Indonesian Journal of Science & Technology Journal, 6 (1), 41-64.

https://doi: 10.17509/ijost.v6i1.xxxx.

Fahad, H. G. 1994. A Study Of Efficiency Of Different Microorganisms In Thorium Sorption From Aqueous Solutions. M.Sc. Thesis. College of Science, Baghdad University, Iraq

Givi, A.N., S.A. Rashid, F.N.A. Aziz, and M.A.M. Salleh. 2010. Assessment of the effects of rice husk ash particle size on strength, water permeability and workability of binary blended concrete. Constr. Build. Mater. 24, 2145–2150. https://doi.org/ 10.10 16/ j.conbuildmat.2010.04.045

Halah, M. S., and M. R. Majeed. 2022. Efficiency assessment of Arabic gum for heavy metal removal from polluted wastewater. Iraqi Journal of Agricultural Sciences, 53(3):570- 577. https://doi.org/10.36103/ijas.v53i3.1565

Hegazi, H. A. 2013. Removal of heavy metals from wastewater using agricultural and industrial wastes as adsorbents. Housing, Building and Research Center Journal, Egypt, 9(3), 276–282. https://doi.org/ 10.101 6/j.hbrcj.2013.08.004.

Hutson, N.D. and R.T.Yang. 1997. Theoretical Basis For The Dubinin-Radushkevitch (D-R) Adsorption Isotherm Equation. Adsorption, 3, 189–195

Hyeon-Yong, L., J. Choong, L. Kyoung-Jae, H. Ki-Chan, L. Jung-Eun, C. Bong-Su, and W. K. Nam. 2009. Adsorption characteristics of heavy metal ions onto chemically modified rice husk and sawdust from aqueous solutions. Korean Journal of Environmental Agriculture. 28(2), 158-164. https://doi.org/10.5338/ KJEA. 2009.28.2.158

Imran, Q., M. A. Hanif, M. S. Riaz, S. Noureen, T.M. Ansari, and H. N. Bhatti. 2012. Coagulation/flocculation of tannery waste-water using immobilized chemical coagulants. J. appl. res. Technol. 10(2), 79-86.

https://doi. org/10.10.10.22201/ icat.166 56423.2012.10.2.392

Iyasele, J.U., and J. I. D. David. 2015. Investigation of the relationship between electrical conductivity and total dissolved solids. International Journal of Engineering Research and Reviews, 3(1), 40-48

Ligate, F. J., and J. E.G. Mdoe. 2015. Removal of heavy metal ions from aqueous solution using rice husks-based adsorbents. Tanz. J. Sci., 41(1), 1-13

Liou, T.-H. 2004. Preparation and characterization of nano-structured silica from rice husk. Materials Science and Engineering: A., 364(1–2), 313-323. https://doi.org/10.10 16/j.msea. 2003.08.045

Majeed, M. R., and H. A., Jasim. 2017. Reducing the turbidity of wastewater by some plant based coagulants. International Journal of Science and Research (IJSR) 6(10), 1014-1018.

https://doi.org/10. 21275/ ART20177334

Majeed, M. R., A. S., Muhammed, and K. A., Rasheed. 2014. The removal of zinc, chromium and nickel from industrial waste water using rice husk. Iraqi Journal of Science, 55(2A), 411-418.

Namasivayam, C., and K., Ranganathan. 1995. Removal of Pb (II), Cd (II) and Ni (II) and mixture of metal ions by adsorption onto waste Fe (III)/Cr (III) hydroxide and fixed bed studies. Environ. Technol, 16, 851–860. https://doi.org/10.1080/09593330.1995.961 8282.

Nisreen J., N., and M. Sirhan. 2021. Comparative study of removal pollutants (heavy metals) by agricultural wastes and other chemical from the aqueous solutions. Iraqi Journal of Agricultural Sciences, 52(2),392-402. https://doi.org/10.36103/ijas.v52i2.1300

Rashid and et al., 2019. Study of toxic heavy metal removal by different chitosan/hyacinths plant composite. Iraqi Journal of Agricultural Sciences, 50(5);1416-1424. https://doi.org/10.36103/ijas.v50i5.809

Rozada, F., M. Otero, A. Morán, A.I. García. 2008. Adsorption of heavy metals onto sewage sludge-derived materials. Bioresource Technology, 99 (14) 6332-6338. https://doi.org/10.1016/j.biortech.2007.12.015

Rungrodnimitchai, S., W. Phokhanusal, and N. Sungkhaho. 2009. Preparation of silica gel from rice husk ash using microwave heating. Journal of Metals, Materials and Minerals, 19 (2), 45-50

Sankar, S., S.K. Sharma, N. Kaur, B. Lee, D.Y. Kim, S. Lee, and H. Jung. 2016. Biogenerated silica nanoparticles synthesized from sticky, red, and brown rice husk ashes by a chemical method. Ceram. Int. 42, 4875–4885.https://doi.org/10.1016/j.ceramint.2015. 11.172

Sarkale, P.S., and A.S. Jadhav.2021. Utilization of rice husk and laterite as a low-cost adsorbent for heavy metal removal through aqueous solution. Innovare Journal of Agri. Sci., 9(4), 1-5. http://dx. doi.org/10. 22159/ijags.2021v9i4.41675

Shinohara, Y. and N. Kohyama. 2004. Quantitative analysis of tridymite and cristobalite crystallized in rice husk ash by heating. Ind. Health, 42(2), 277-85. https:// doi:10.2486/indhealth.42.277

Sillanpää, M., Ncibi, M.C., Matilainen, A., Vepsäläinen, M. 2018. Removal of natural organic matter in drinking water treatment by coagulation: A comprehensive review. Chemosphere, 190, 54–71. https:// doi.org/10.10.1016/j.chemosphere.2017.09.113

Thuadaij, N., and A. Nuntiya. 2008. Preparation of nanosilica powder from rice husk ash by precipitation method. Chiang Mai J. Sci.; 35(1), 206-211

Williams, M., R.S. Kookana, A. Mehta, S.K.Yadav, B.L.Tailor, and B. Maheshwari. 2019. Emerging contaminants in a river receiving untreated wastewater from an Indian urban centre. Sci. Total Environ, 647, 1256–1265.https://doi.org/10.1016/j. scitotenv. 2018. 08. 084

Wurtsbaugh, W.A., H.W. Paerl, and W.K. Dodds. 2019. Nutrients, eutrophication and harmful algal blooms along the freshwater to marine continuum. Wiley Interdiscip Rev. Water. 6(5), 1-27. https://doi.org/ 10.1002/ wat2.1373.

Downloads

Published

2024-02-25

Issue

Section

Articles

How to Cite

M. R. Majeed, Wafaa W. AL-Qaysi, & F.H.Abdulla. (2024). THE EFFICIENCY OF GUM-SILICA CMPOSITE FOR REMOVING OF WASTEWATER TURBIDITY. IRAQI JOURNAL OF AGRICULTURAL SCIENCES, 55(1), 329-341. https://doi.org/10.36103/d96s6950

Similar Articles

11-20 of 103

You may also start an advanced similarity search for this article.